Bis[μ-4-(2-oxidobenzylidene)thiosemicarbazidato-κ4 S,N 1,O:O]bis[(pyridine-κN)zinc]
نویسندگان
چکیده
In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio-semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom. Both Zn(II) atoms are five-coordinated; the coordination polyhedra are close to square pyramids, with the pyridine N atoms at apical positions. Two inter-molecular N-H⋯N and one relatively weak N-H⋯S hydrogen bond, together with C-H⋯S weak inter-actions, connect the mol-ecules into a three-dimensional network.
منابع مشابه
Bis{μ-2-[(2-oxidobenzylidene)aminomethyl]phenolato-κ3 O,N,O′}bis[(pyridine-κN)zinc(II)]
In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) u...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012